Friday, March 2, 2018

Comparison of hydrocolloid properties(methy,pectin,xanthan,E461,E440,E401,E415)

Comparison of hydrocolloid properties:

Keywords:methy,pectin,xanthan,E461,E440,E401,E415

Name methyl cellulose (E461) pectin (E440)
low methoxyl (LM)
pectin (E440)
high methoxyl (HM)
sodium alginate (E401) xanthan (E415)
Origin
a modified polysaccharide derived
from cellulose rich plants.
polysaccharide derived from citrus
peel and apple pomace.
polysaccharide derived from citrus
peel and apple pomace.
polysaccharide extracted from
brown algae.
polysaccharide obtained by
fermentation of
Xanthomonas
campestris
Texture thermoreversible soft elastic gel
when heated; helps form and
stabilize foams when cold
thermoreversible gels thermoirreversible gels thermoirreversible gel in presence of
calcium ions; shear-thinning
thickener in absence of calcium
high viscosity, shear-thinning;
thermoreversible soft elastic gels w.
locust bean gum or konjac
Clarity clear, transparent clear, transparent clear, transparent clear, mostly transparent
Dispersion
hot or cold water, use slow speed to
avoid foaming; mix with small
amount of hot water to avoid lumps
and stir into the rest of the cold
water
cold water; d. can be improved by
mixing with sugar (3-5x)
cold water; d. can be improved by
mixing with sugar (3-5x)
cold water; d. can be improved by
mixing with sugar (3-5x); add. of
acidic liquids may cause
precipitation of alginic acid
cold or hot water; d. can be
improved by mixing with sugar (10x)
or glycerol, alcohol or vegetable oil.
Hydration
(dissolution)

cold water, leave over night; add salt
after complete hydration
cold or hot water cold or hot water; will not dissolve
if > 25% sugar
cold or hot water; if cold, allow to
hydrate for a
couple of hours
cold or hot water; does not hydrate
at high sugar concentrations
(>65%).

pH

2-13

2.5-5.5

2.5-4

2.8-10

1-13
Setting
gels when heated to 50-60 °C

40-85 °C (depending on pH and
degree of methoxylation)
independant of temp.
Melting
melts below the setting temperature
yes no
no (but prolonged heating at
low/high pH will destabilize gel)
Promoter salt lowers setting temperature
requires calcium ions for gelling; can
gel in presence of milk (0.6-0.9%
pectin required)
requires acidity (pH < 3.5) and high
sugar contents for gelling (60-80%
soluble solids, mainly sugar)
requires calcium for gelling
Inhibitor alcohol rises setting temperature high sugar concentrations, low pH,
alcohol

precipitates as alginic acid at pH < 4
(is corrected by add. of sodium
citrate); gels at too high ion/salt
concentrations
Tolerates acids, bases
up to ~50% ethanol (d. and hydrate
in water before addition of alcohol)
acids/bases, salts, heating,
enzymes, up to 60% ethanol
Viscosity of
solution
low when cold, high when hot low low low in neutral water, high at lower
pH (< 5.5)
high (independent of temperature)
Typical
concentration
1-2% for gels; [0.26-3.4%]* [0.15-3.1%]* [0.15-6.3%]* 0.5-1% for normal spherification;
[0.3-5%]*

0.25% thin running sauce, 0.7-1.5%
thick sauces, 0.5-0.8% foams; [0.07-
1%]*
Synergies guar, locust bean gum, konjac, tara
Syneresis yes yes yes yes

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